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Highly Compatible Metal and Enzyme Catalysts for Efficient Dynamic Kinetic Resolution of Alcohols at Ambient Temperature

✍ Scribed by Belén Martín-Matute; Michaela Edin; Krisztián Bogár; Jan-E. Bäckvall

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
178 KB
Volume
116
Category
Article
ISSN
0044-8249

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Aminocyclopentadienyl Ruthenium Chloride: Catalytic Racemization and Dynamic Kinetic Resolution of Alcohols at Ambient Temperature
✍ Jun Ho Choi; Yu Hwan Kim; Se Hyun Nam; Seung Tae Shin; Mahn-Joo Kim; Jaiwook Par 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 102 KB

Dynamic kinetic resolution (DKR) is an attractive method for the complete transformation of a racemic mixture into a single enantiomer. [1] The DKR of secondary alcohols is a prominent example, for which transition-metal-catalyzed racemization is coupled with enzymatic acylation. [2] In particular,