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New Developments in Nucleophilic Additions to Nitrones

✍ Scribed by Pedro Merino

Book ID
101987901
Publisher
John Wiley and Sons
Year
2006
Weight
8 KB
Volume
37
Category
Article
ISSN
0931-7597

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Nucleophilic Addition of Nitrones to Ket
Nucleophilic Addition of Nitrones to Ketones: Development of a New Catalytic Asymmetric Nitrone-Aldol Reaction
✍ Anders BΓΈgevig; Kurt V. Gothelf; Karl Anker JΓΈrgensen πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 210 KB πŸ‘ 2 views

A new organic reaction has been discovered in which nitrones react with carbonyl compounds in an aldoltype reaction to give functionalized beta-hydroxynitrones. The alpha-carbon atom of the nitrone undergoes a nucleophilic addition reaction to electron-deficient ketones, such as alpha-ketoesters, al