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New data on the mechanism of hydrogen peroxide decomposition in acetic acid in the presence of vanadyl and cobalt (II) acetylacetonates

✍ Scribed by A. P. Pokutsa; A. B. Zaborovskiy; D. S. Maxym; J. Muzart

Publisher
Springer
Year
2010
Tongue
English
Weight
184 KB
Volume
59
Category
Article
ISSN
1573-9171

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## Abstract Iron complexes (tpa)Fe(OTf)~2~ (1) and (bpmen)Fe(OTf)~2~ (2) [tpa=tris‐(2‐pyridylmethyl)amine; bpmen=__N,Nβ€²__‐bis‐(2‐pyridylmethyl)‐__N,N′‐__dimethyl‐1,2‐ethylenediamine] were found to catalyze the __in situ__ formation of AcOOH from H~2~O~2~ and AcOH in the course of olefin oxidations.