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Rates of formation of peroxyacetic acid from hydrogen peroxide and acetic acid in the presence of metal(IV) phosphates

✍ Scribed by Graça O Rocha; Robert A.W Johnstone; Beverley F Hemming; Preciosa J.C Pires; J.Philip Sankey

Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
102 KB
Volume
186
Category
Article
ISSN
1381-1169

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Higher alkanes (cyclohexane, n-pentane, n-heptane, methylbutane, 2-and 3methylpentanes, 3-methylhexane, cis-and trans-deealins) are oxidized at 20 °C by H202 in air in acetonitrile (or nitromethane) solution in the presence of the manganese(IV) salt [L2Mn203](PF6)2 (L = 1,4,7-trimethyl-1,4-7-triazac