✦ LIBER ✦
ChemInform Abstract: Efficient Stereoselective Oxygenation of Alkanes by Peroxyacetic Acid or Hydrogen Peroxide and Acetic Acid Catalyzed by a Manganese(IV) 1,4,7-Trimethyl-1,4,7-triazacyclononane Complex.
✍ Scribed by J. R. LINDSAY SMITH; G. B. SHUL'PIN
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 35 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Efficient Stereoselective Oxygenation of Alkanes by Peroxyacetic Acid or Hydrogen Peroxide and Acetic Acid Catalyzed by a Manganese( IV) 1,4,4,-The oxidation of unfunctionalized alkanes such as (I) is achieved by peroxyacetic acid (or H 2 O 2 /AcOH) in the presence of a dinuclear Mn(IV) complex as catalyst. The process gives large turnovers and can occur with high degree of retention of stereochemistry at the tertiary carbon centers. -(LINDSAY