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New Chiral Pyrrolidine- and Pyrrolidinoneethanols for Enantioselective Addition of Diethylzinc to Arylaldehydes.

✍ Scribed by Yuko Okuyama; Hiroto Nakano; Mayumi Igarashi; Chizuko Kabuto; Hiroshi Hongo


Book ID
101947937
Publisher
John Wiley and Sons
Year
2003
Weight
95 KB
Volume
34
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES


New chiral catalysts for the highly enan
✍ Myung-Jong Jin; Sum-Jin Ahn; Kyoung-Soo Lee πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 French βš– 175 KB

Optically active amino thioacetate derivatives of (+l-norephedrine were found to act as effective catalysts for enantioselective addition of diethylzinc to aldehydes. This reaction provided optically active secondary alcohols with e.e. of up to >99%.

Stereocontrolled enantioselective additi
✍ Yong Hae Kim; Doo Han Park; Il Suk Byun πŸ“‚ Article πŸ“… 1992 πŸ› John Wiley and Sons 🌐 English βš– 294 KB

## Abstract The new chiral β‐aminoalcohols of indolinylmethanols (__1__) and their reduced derivatives (__2__) were synthesized from (__S__)‐indoline‐2‐carboxylic acid. Both (__R__) and (__S__) enantiomers of the optically active secondary alcohols have been successfully obtained in high enantiomer

Chiral ferrocenyl amino alcohols for ena
✍ StΓ©phanie Bastin; Mihaela Ginj; Jacques Brocard; Lydie PΓ©linski; Guy Novogrocki πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 English βš– 262 KB

Optically active ferrocenyl amino alcohols have been prepared from commercially available L-alaninol, L-leucinol and L-valinol. They have been utilized as chiral ligands in the catalytic addition of diethylzinc to aldehydes. The influence of the substituents on the stereogenic centers of the ligand