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New Catalytic Reactions via the π-Allylpalladium Azide Complexes

✍ Scribed by Shin Kamijo; Yoshinori Yamamoto

Publisher
John Wiley and Sons
Year
2004
Weight
8 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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Kinetics and Mechanisms of the Reactions of π-Allylpalladium Complexes with Nucleophiles
✍ Oliver Kuhn; Herbert Mayr 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 133 KB 👁 1 views

Which nucleophiles are capable of attacking the allyl ligand of the Pd-stabilized allyl cation 1? This question is answered by the electrophilicity parameter of 1 which is derived from kinetic investigations.