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New Access to Fluorinated Ketoglycolic Acid Derivatives from Trifluoropyruvamides.

✍ Scribed by Thomas Colin; Laurent El Kaim; Laetitia Gaultier; Laurence Grimaud; Laurent Gatay; Valerie Michaut

Book ID
101965729
Publisher
John Wiley and Sons
Year
2004
Weight
17 KB
Volume
35
Category
Article
ISSN
0931-7597

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Fluorinated succinic acid derivatives fr
Fluorinated succinic acid derivatives from new refrigerants via ozonolysis of haloalkenes
✍ Samantha J Brown; Stuart Corr; Jonathan M Percy πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 160 KB

Fluoro-and di-Β―uoro allylic alcohols obtained from HFC-134a and HCFC-133a were transformed through [3,3]-sigmatropic rearrangements into 3-Β―uoro-4-halo-4-alkenoates with variable substitution at the 2-and 3-positions. Ozonolysis of the haloalkenes aorded the corresponding acyl halides which could be