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New access to fluorinated glycolic acid derivatives from trifluoropyruvamides

✍ Scribed by Laurent El Kaim; Stephane Guyoton; Christophe Meyer

Book ID
103402030
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
174 KB
Volume
37
Category
Article
ISSN
0040-4039

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Fluoro-and di-Β―uoro allylic alcohols obtained from HFC-134a and HCFC-133a were transformed through [3,3]-sigmatropic rearrangements into 3-Β―uoro-4-halo-4-alkenoates with variable substitution at the 2-and 3-positions. Ozonolysis of the haloalkenes aorded the corresponding acyl halides which could be