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Neptunium (V) Oxidation by Nitrous Acid in Nitric Acid

โœ Scribed by Colin Gregson; Colin Boxall; Michael Carrott; Scott Edwards; Mark Sarsfield; Robin Taylor; David Woodhead


Book ID
119352804
Publisher
Elsevier
Year
2012
Weight
185 KB
Volume
7
Category
Article
ISSN
1876-6196

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Oxidation of benzyl alcohols by nitrous
โœ David S. Ross; Chee-Liang Gu; Georgina P. Hum; Ripudaman Malhotra ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 505 KB

We have studied the oxidation of benzyl alcohols by nitrous and nitric acid in sulfuric acid media. The oxidation by nitrous acid is rapid and has an activation energy of 10.6 -t 0.8 kcal mol-'. A Hammett plot of logkp vs. u -is linear with a p value of -1.4. The oxidation by nitric acid in sulfuric