Oxidation of Urea with Nitrous Acid in Nitric Acid Solutions
โ Scribed by K. N. Dvoeglazov; V. I. Marchenko
- Publisher
- Springer
- Year
- 2005
- Tongue
- English
- Weight
- 59 KB
- Volume
- 47
- Category
- Article
- ISSN
- 1066-3622
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๐ SIMILAR VOLUMES
We have studied the oxidation of benzyl alcohols by nitrous and nitric acid in sulfuric acid media. The oxidation by nitrous acid is rapid and has an activation energy of 10.6 -t 0.8 kcal mol-'. A Hammett plot of logkp vs. u -is linear with a p value of -1.4. The oxidation by nitric acid in sulfuric
Aqueous acid solutions of nitric oxide (NO) are used as a source for this species in chemical and biological experiments. To utilize known quantities of NO, it is necessary to determine the escape rate of NO from these solutions. Escape rates at constant temperature are concentration dependent. The