We have studied the oxidation of benzyl alcohols by nitrous and nitric acid in sulfuric acid media. The oxidation by nitrous acid is rapid and has an activation energy of 10.6 -t 0.8 kcal mol-'. A Hammett plot of logkp vs. u -is linear with a p value of -1.4. The oxidation by nitric acid in sulfuric
โฆ LIBER โฆ
Reduction of Nitrous Oxide Emissions from Nitric Acid Plants
โ Scribed by M. Schwefer; M. Groves; R. Maurer
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- German
- Weight
- 63 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0009-286X
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A procedure based on that of Van Slyke and LoMonte (Microchem. J. 14,[608][609][610][611][612][613][614][615][616][617][618][619][620][621][622][623][624][625][626] 1969) is described for the mass spectrometric analysis of 15N in nitrate extracted from plant tissue. The extract is evaporated to dry