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A synergetic effect in nitrous acid formation by sonolysis of nitric acid in the presence of nitrous oxide

โœ Scribed by S. I. Nikitenko; A. F. Seliverstov


Book ID
110275849
Publisher
Springer
Year
2000
Tongue
English
Weight
271 KB
Volume
49
Category
Article
ISSN
1573-9171

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Oxidation of benzyl alcohols by nitrous
โœ David S. Ross; Chee-Liang Gu; Georgina P. Hum; Ripudaman Malhotra ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 505 KB

We have studied the oxidation of benzyl alcohols by nitrous and nitric acid in sulfuric acid media. The oxidation by nitrous acid is rapid and has an activation energy of 10.6 -t 0.8 kcal mol-'. A Hammett plot of logkp vs. u -is linear with a p value of -1.4. The oxidation by nitric acid in sulfuric