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Neighboring amide group participation in ester aminolysis in aprotic solvents

✍ Scribed by Kőmives, T. ;Márton, A. F. ;Dutka, F.

Book ID
112688784
Publisher
Springer
Year
1976
Tongue
English
Weight
175 KB
Volume
4
Category
Article
ISSN
0133-1736

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Kinetics and mechanism of aminolysis of
Kinetics and mechanism of aminolysis of aliphatic esters in aprotic solvents
✍ Agu-Tõnis Talvik; Ants Tuulmets; Evi Vaino 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 52 KB 👁 2 views

Kinetic studies were carried out on the aminolysis reactions of substituted aliphatic esters in a variety of aprotic solvents. The reaction rate is strongly affected by inductive and steric effects of substituents in the acyl group, rising more than 10 4 -fold from cyanoacetate to trifluoroacetate.