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Nature of the Chemical Bond in Polypnictides: The Lone Pair Aromatic Anions P 42- and As 42-

✍ Scribed by Kraus, Florian; Hanauer, Tobias; Korber, Nikolaus


Book ID
118038765
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
438 KB
Volume
45
Category
Article
ISSN
0020-1669

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Chemical Bond in the Cyclic Anions P64βˆ’
✍ Florian Kraus; Tobias Hanauer; Nikolaus Korber πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 451 KB πŸ‘ 3 views

The bonding in the As 6 4Γ€ ion is studied in the unusually low-coordination environment provided by the compound {Rb[18]crown-6)} 2 Rb 2 As 6 β€’6 NH 3 . Theoretical analysis of the related P 6 4Γ€ ion indicates an unusual PΒΌP bond which contains major contributions from the lone pairs. Outside a highl