𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Nature and reactivity of intermediates in the auto-oxidation of iron (II) in aqueous acid media

✍ Scribed by C. Domingo; R. Rodríguez-Clemente; M.A. Blesa


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
644 KB
Volume
59
Category
Article
ISSN
0167-2738

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Oxidation of formic acid by bromine in a
✍ Peter Herbine; James G. Brummer; Richard J. Field 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 444 KB 👁 1 views

Spectrophotometric methods were used to investigate the rate of the reaction of Br:! with HCOOH in aqueous, acidic media. The reaction products are Br-and COa. The kinetics of this reaction are complicated by both the formation of Br3-as Bris formed and the dissociation of HCOOH into HCOO-and H+. Pr

The kinetics and mechanism of the oxidat
✍ M. A. Brusa; A. J. Colussi 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 326 KB 👁 1 views

The reaction between formic acid and bromine in strongly acid aqueous media at 298 K Brz + HCOOH -2 Br-+ 2 H+ + COz was studied by absorption spectrophotometry (A = 447 nm). Reaction rates, expressed as H = -d[Brz]/dt, depend on the concentrations of HCOOH (0.3-2.4M), Br2[(2.7-13.6) X 10-3M], H+ (0.

Mechanism of oxidation of iron(II) chela
✍ Parupalli J. Lakshmi; Kamatala C. Rajanna; Pondichery K. Saiprakash 📂 Article 📅 1996 🏛 Springer 🌐 English ⚖ 534 KB

Oxidation of the Fe n chelates [FeL l (L = phen or bipy) by Cr w and Mn TM in H2SO 4 medium was found to proceed through the formation of a bimetallic insertion complex which decomposes in the slow step, followed by electron transfer from [FeLl to the oxidant. The reactions are catalysed by both ani