The kinetics of the oxidation of dimethylsulfoxide by Cerium(IV) in perchloric acid has been investigated spectrophotometrically. The water role has been elucidates by using acidity criteria. A tentative mechanism consistent with the kinetics is dis- ## Kinetische Untersuchung der Oxidation von Dim
The oxidation of water by Np(VII) in aqueous perchloric acid media
✍ Scribed by James C Sullivan; A.J Zielan
- Publisher
- Elsevier Science
- Year
- 1969
- Weight
- 163 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0020-1650
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Spectrophotometric methods were used to investigate the rate of the reaction of Br:! with HCOOH in aqueous, acidic media. The reaction products are Br-and COa. The kinetics of this reaction are complicated by both the formation of Br3-as Bris formed and the dissociation of HCOOH into HCOO-and H+. Pr
The reaction between formic acid and bromine in strongly acid aqueous media at 298 K Brz + HCOOH -2 Br-+ 2 H+ + COz was studied by absorption spectrophotometry (A = 447 nm). Reaction rates, expressed as H = -d[Brz]/dt, depend on the concentrations of HCOOH (0.3-2.4M), Br2[(2.7-13.6) X 10-3M], H+ (0.
## Abstract The kinetics of oxidation of several substituted quinols by a series of Tris(1,10‐phenanthroline)iron(III) complexes has been investigated with a stopped‐flow technique at 6.0 and 20.0°C. The reactions were found to be first order on both reactants and independent of acidity. The second
## Abstract The kinetics and mechanism of the silver(II) oxidation of methanol, ethanol, 1‐propanol, 1‐methyl‐ ethanol, 1‐butanol, 2‐methyl‐1‐propanol, 2‐butanol, 2‐methyl‐2‐propanol, D~4~‐methanol, and D~6~‐methanol have been investigated at 8.0 and 20.0°C in aqueous perchloric acid media (1.00 ≤