## Abstract Sterically hindered secondary aliphatic and tertiary alcohols as well as amines and thiols are resistant to the reagent system.
Nanocrystalline TiO2 as an efficient and reusable catalyst for the chemoselective trimethylsilylation of primary and secondary alcohols and phenols
β Scribed by Farhad Shirini; Meysam Alipour Khoshdel; Masoumeh Abedini; Seyyed Vahid Atghia
- Book ID
- 113523164
- Publisher
- Chinese Electronic Periodical Services
- Year
- 2011
- Tongue
- English
- Weight
- 394 KB
- Volume
- 22
- Category
- Article
- ISSN
- 1001-8417
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## Abstract In the present work, the application of electronβdeficient tetraphenylporphyrinatovanadium(IV) trifluoromethanesulfonate, [V^IV^(TPP)(OTf)~2~], in the trimethylsilylation of alcohols and phenols with hexamethydisilazane (HMDS) is reported. This new V(IV) catalyst was used as an efficien
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v