ChemInform Abstract: Nanocrystalline TiO2 as an Efficient and Reusable Catalyst for the Chemoselective Trimethylsilylation of Primary and Secondary Alcohols and Phenols.
β Scribed by Farhad Shirini; Meysam Alipour Khoshdel; Masoumeh Abedini; Seyyed Vahid Atghia
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 45 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
β¦ Synopsis
Abstract
Sterically hindered secondary aliphatic and tertiary alcohols as well as amines and thiols are resistant to the reagent system.
π SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
## Abstract In the present work, the application of electronβdeficient tetraphenylporphyrinatovanadium(IV) trifluoromethanesulfonate, [V^IV^(TPP)(OTf)~2~], in the trimethylsilylation of alcohols and phenols with hexamethydisilazane (HMDS) is reported. This new V(IV) catalyst was used as an efficien