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ChemInform Abstract: Electron-Deficient Vanadium(IV) Tetraphenylporphyrin: A New, Highly Efficient and Reusable Catalyst for Chemoselective Trimethylsilylation of Alcohols and Phenols with Hexamethyldisilazane.

✍ Scribed by Majid Moghadam; Iraj Mohammadpoor-Baltork; Shahram Tangestaninejad; Valiollah Mirkhani; Ahmad Reza Khosropour; S. Abdolmanaf Taghavi


Publisher
John Wiley and Sons
Year
2011
Weight
39 KB
Volume
43
Category
Article
ISSN
0931-7597

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## Abstract In the present work, the application of electron‐deficient tetraphenylporphyrinatovanadium(IV) trifluoromethanesulfonate, [V^IV^(TPP)(OTf)~2~], in the trimethylsilylation of alcohols and phenols with hexamethydisilazane (HMDS) is reported. This new V(IV) catalyst was used as an efficien

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