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NAD(P) + −NAD(P)H Models. 90. Stereoselection Controlled by Electronic Effect of a Carbonyl Group in Oxidation of NAD(P)H Analog

✍ Scribed by Ohno, Atsuyoshi; Oda, Seiji; Ishikawa, Yoshiteru; Yamazaki, Norimasa


Book ID
127007882
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
91 KB
Volume
65
Category
Article
ISSN
0022-3263

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NAD(P)+–NAD(P)H models. 84. Stereochemis
✍ Atsuyoshi Ohno; Norimasa Yamazaki; Akihiro Tsutsumi; Yuji Mikata; Mutsuo Okamura 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 542 KB

## 2,3-Dihydro-2,2,4-trimethylthieno[3,2-b]pyridinium I-oxide iodide (1) has been reacted with various inorganic and organic hydride donors. It has been found that the stereochemistry of reaction is controlled by the orientation of the sulfinyl dipole, and the relative bulkiness of substituents pl