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ChemInform Abstract: NAD(P)+-NAD(P)H Models. Part 87. Nonsteric Stereochemistry Controlled by a Carbonyl Dipole.

✍ Scribed by A. OHNO; A. TSUTSUMI; N. YAMAZAKI; M. OKAMURA; Y. MIKATA; M. FUJII


Book ID
112039228
Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
27
Category
Article
ISSN
0931-7597

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NAD(P)+–NAD(P)H models. 84. Stereochemis
✍ Atsuyoshi Ohno; Norimasa Yamazaki; Akihiro Tsutsumi; Yuji Mikata; Mutsuo Okamura πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 542 KB

## 2,3-Dihydro-2,2,4-trimethylthieno[3,2-b]pyridinium I-oxide iodide (1) has been reacted with various inorganic and organic hydride donors. It has been found that the stereochemistry of reaction is controlled by the orientation of the sulfinyl dipole, and the relative bulkiness of substituents pl