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Nachbarǵruppeneffekte bei der Hydrolyse von Acetonyl-Estern

✍ Scribed by Elsbeth Schätzle; Hans Urheim; Max Thürkauf; Max Rottenberg

Publisher
John Wiley and Sons
Year
1963
Tongue
German
Weight
445 KB
Volume
46
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

Kinetic studies revealed that esters of hydroxyacetone undergo alkaline hydrolysis with participation of neighbouring groups, its rate being higher by a factor of at least 20 than could have been anticipated on the basis of inductive effects alone. The mechanism is discussed in terms of either nucleophilic or electrophilic intra‐molecular catalysis.

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