𝔖 Bobbio Scriptorium
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N-(Pyridin-2-yl)hydrazinecarbothio­amide

✍ Scribed by Rapheal, P. F. ;Manoj, E. ;Kurup, M. R. Prathapachandra ;Suresh, E.

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
230 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, C 6 H 8 N 4 S, crystallizes as the thione tautomer, with intramolecular NÁ Á ÁH-N and SÁ Á ÁH-N hydrogen bonds, andstacking along the b axis. Intermolecular NÁ Á ÁH-N hydrogen bonds link the molecules into one-dimensional sheets stacked along the c axis.

📜 SIMILAR VOLUMES

(E)-N-[2-(Pyridin-2-yl)isoindolin-1-ylid
(E)-N-[2-(Pyridin-2-yl)isoindolin-1-ylidene]pyridin-2-amine
✍ Zhu, Li-Na ;Gao, Shan ;Huo, Li-Hua ;Zhao, Hui 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 755 KB

A new bis(pyridyl) compound, C 18 H 14 N 4 , was prepared by the reaction of phthalaldehyde and 2-aminopyridine in toluene. In the crystal structure,stacking interactions exist between two adjacent molecules. ## Related literature Two corresponding complexes with 5-methyl-4,5-dihydroisoxazol-3-yl

N-(6-Bromopyridin-2-yl)pyridin-2-amine
N-(6-Bromopyridin-2-yl)pyridin-2-amine
✍ Wu, Jian 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 280 KB

In the title compound, C~10~H~8~BrN~3~, the dihedral angle between the pyridine ring planes is 6.10 (15)°. In the crystal structure, the molecules are linked by N—H...N hydrogen bonds, leading to chains.