In the crystal structure of the title compound, C~14~H~11~FN~2~OS, the molecules form centrosymmetric hydrogen-bonded dimers, with the S atom forming an intermolecular hydrogen bond with the H atom of an NH group.
N-(N-Phenylbenzimidoyl)thiobenzanilide
✍ Scribed by Naumov, Pan˘ce ;Ristovska, Nata˘sa ;Anastasova, Frosa ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 182 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, C~12~H~16~N~2~OS, adopts a __trans__–__cis__ configuration of the 3-methylbutyryl and phenyl groups, respectively, with respect to the thiono S atom, across the thiourea C—N bonds. An intramolecular N—H...O hydrogen bond is formed and intermolecular N—H...O and N—H...S interactio
The NCS 2 groups in the title compound, C 20 H 23 N 2 S 4 , are approximately perpendicular to each other, forming a dihedral angle of 80.10 (7) . The S-S bond length is 2.0086 (14) A ˚and the distance between the two terminal S atoms is 3.940 (3) A ˚.
The title compound, C~13~H~12~N~2~OS, was prepared by the reaction of (4-pyridyl)methanol with phenyl isothiocyanate and NaOH in a 1,4-dioxane solution. The asymmetric unit contains two independent molecules. The molecular structure and packing are stabilized by N—H...N intermolecular hydrogen-bond
The molecule in the title compound, C~15~H~12~Cl~2~N~2~OS, adopts a __trans__–__cis__ configuration with respect to the positions of the phenylacetyl and 3,4-dichlorophenyl groups relative to the S atom across their C—N bonds. In the crystal structure, the molecules are linked by N—H...O and C—H...O
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.045 wR factor = 0.125 Data-to-parameter ratio = 17.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.