The V V atom in the title complex, [V(C 16 H 12 C 12 N 2 O 4 )-(C 13 H 10 NO 2 )O], is coordinated by two O atoms and one N atom of the tridentate hydrazone ligand, and by two O atoms of the bidentate hydroxamate co-ligand, thus de®ning a distorted octahedral VO(ONO)(ON) geometry.
(N-Hydroxy-N-phenylbenzamidato-κ2O,O′)oxo[salicylaldehyde (4-nitrobenzoyl)hydrazonato-κ3O,N,O′]vanadium(V)
✍ Scribed by Gao, Shan ;Huo, Li-Hua ;Zhang, Xian-Fa ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 170 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Acta Cryst. (2005). E61, m738-m739 Gao et al. [V(C 14 H 9 N 3 O 4 )(C 13 HNO 3 )O] m739 Figure 1 ORTEPIII (Burnett & Johnson, 1996) molecular view of (I), with the atom-labelling scheme. Displacement ellipsoids are drawn at the 30% probability level. H atoms have been omitted for clarity.
📜 SIMILAR VOLUMES
In the title centrosymmetric dimeric complex, [V 2 (C 12 H 13 -N 3 O 3 ) 2 (CH 3 O) 2 O 2 ], each V V atom is six-coordinated by one oxo O atom, two N atoms and one O atom of the tridentate hydrazone ligand and two O atoms of two methoxo groups, leading to a distorted octahedral environment. Two V V