The molecule in the title compound, C~11~H~12~Cl~2~N~2~OS, adopts a __trans__–__cis__ configuration of the butanoyl and 3,4-dichlorophenyl groups with respect to the thiono S atom across the thiourea C—N bonds. In the crystal structure, molecules are linked into a two-dimensional network by N—H...S
N-Butanoyl-N′-(4-nitrophenyl)thiourea
✍ Scribed by Yusof, M. Sukeri M. ;Saadum, Zati Iwani M. ;Yamin, Bohari M.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 784 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The molecule in the title compound, C 11 H 13 N 3 O 3 S, adopts a trans-cis configuration with respect to the positions of the butanoyl and 4-nitrophenyl groups relative to the S atom across their respective C-N bonds. In the crystal structure, molecules are linked into two-dimensional networks by N-HÁ Á ÁS and C-HÁ Á ÁO interactions.
Related literature
For some related structures, see: Yusof et al. (2006Yusof et al. ( , 2007a,b),b).
📜 SIMILAR VOLUMES
In the crystal structure of the title compound, C 15 H 11 Cl 2 N 3 O 4 S, there are two intramolecular N-HÁ Á ÁO and one C-HÁ Á ÁS hydrogen bonds and a weak intermolecular C-HÁ Á ÁO hydrogen bond.
In the title compound, C~16~H~15~N~3~O~4~, the dihedral angle between the two benzene ring is 16.66 (6)°. The molecule crystallizes in a centrosymmetric space group and hence does not exhibit nonlinear optical second harmonic generation properties. The angle between the mean plane of the 4-nitrophen
## Electrochemical fluorination of 4-(perfluoro-n-butylj-n-butanoyl chloride produces perfluorooctanoyl fluoride in higher yields than those obtained from n-octanoyl chloride, which is the usual starting material. In particular, one of the by-products of the industrial process, the cyclic perfluor
Molecules of the title compound, C 16 H 16 N 2 O 3 S, are linked by N-HÁ Á ÁS hydrogen bonds to form centrosymmetric dimers [NÁ Á ÁS = 3.4501 (13) A ˚]. The N 0 -phenyl and N-phenyl rings are twisted by 52.7 (1) and 23.3 (1) , respectively, from the essentially planar -NHC( S)NC( O)-moiety.