N-(2,4-Dichlorophenoxyacetyl)-N′-(4-nitrophenyl)thiourea
✍ Scribed by Li, Qian-Jin ;Yang, Chun-Long ;Xie, Xue-Qun ;Luo, Jin-Xiang
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 97 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the crystal structure of the title compound, C 15 H 11 Cl 2 N 3 O 4 S, there are two intramolecular N-HÁ Á ÁO and one C-HÁ Á ÁS hydrogen bonds and a weak intermolecular C-HÁ Á ÁO hydrogen bond.
📜 SIMILAR VOLUMES
In the title compound, C~10~H~13~Cl~2~O~4~PS, all bond lengths and angles are normal. The P atom is in a distorted tetrahedral configuration. In the crystal structure, intermolecular N—H...O hydrogen bonds link the molecules into chains running along the __b__ axis.
The molecule in the title compound, C~15~H~12~Cl~2~N~2~OS, adopts a __trans__–__cis__ configuration with respect to the positions of the phenylacetyl and 3,4-dichlorophenyl groups relative to the S atom across their C—N bonds. In the crystal structure, the molecules are linked by N—H...O and C—H...O
The title compound, C 14 H 10 ClN 3 O 4 , was obtained by the reaction of N-(4-chlorophenyl)-N 0 -(4-nitrobenzoyl)thiourea with cupric chloride dihydrate. Intermolecular N-HÁ Á ÁO hydrogen bonds link the molecules into centrosymmetric dimers. The crystal packing is further stabilized by weak C-HÁ Á
In the title compound, C 8 H 10 N 2 OS, the dihedral angle between the benzene ring and the thiourea group is 59.23 (4) . Molecules are linked via N-HÁ Á ÁO/S hydrogen bonds, forming a two-dimensional network.