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N-Bromoacetamide—A New Nitrogen Source for the Catalytic Asymmetric Aminohydroxylation of Olefins

✍ Scribed by Dr. Milan Bruncko; Dr. Gunther Schlingloff; Prof. K. Barry Sharpless


Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
511 KB
Volume
36
Category
Article
ISSN
0044-8249

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✦ Synopsis


alcoholsasymmetric catalysis . asymmetric aminohydroxylationhaloamides * homogeneous catalysis

[l] a) G.


📜 SIMILAR VOLUMES


ChemInform Abstract: N-Chloro-N-sodio-2-
✍ K. L. REDDY; K. R. DRESS; K. B. SHARPLESS 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

Asymmetric aminohydroxylation of the alkenes (I) and (IV) is performed with the title carbamate using an asymmetric catalyst. The silyl protecting group of the products is readily cleaved with fluoride under mild conditions. -