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ChemInform Abstract: tert-Butylsulfonamide. A New Nitrogen Source for Catalytic Aminohydroxylation and Aziridination of Olefins.

โœ Scribed by Alexander V. Gontcharov; Hong Liu; K. Barry Sharpless

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: N-Chloro-N-sodio-2-trimethylsilyl Ethyl Carbamate: A New Nitrogen Source for the Catalytic Asymmetric Aminohydroxylation.
โœ K. L. REDDY; K. R. DRESS; K. B. SHARPLESS ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 33 KB ๐Ÿ‘ 1 views

Asymmetric aminohydroxylation of the alkenes (I) and (IV) is performed with the title carbamate using an asymmetric catalyst. The silyl protecting group of the products is readily cleaved with fluoride under mild conditions. -