In the crystal structure of the title compound, C 24 H 29 BN 2 , the coordination around both the B and N atoms is distorted tetrahedral. The ®ve-membered ring adopts an envelope conformation, with the ¯ap atom, B, displaced by 0.629 (6) A Ê from the plane of the other four atoms.
{[N-Benzyl-N-(2-pyridyl)amino]methylene}diphenylphosphine oxide
✍ Scribed by Cui, Da-Jun ;Zeng, Xianshun ;Leng, Xuebing ;Xu, Fengbo ;Zhang, Zhengzhi
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 183 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.047 wR factor = 0.120 Data-to-parameter ratio = 14.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 294 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.057 wR factor = 0.145 Data-to-parameter ratio = 19.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C 12 H 12 N 2 O 2 , crystallizes in the triclinic space group P1 with two crystallographically independent molecules in the asymmetric unit. These two molecules differ slightly in the relative orientation of the phenyl and oxazoline rings. The molecular packing in the crystal is