✦ LIBER ✦

N-Atom measurements in high temperature C2N2/NO/Ar reaction systems

✍ Scribed by K. Natarajan; D. Woiki; P. Roth

Publisher: John Wiley and Sons
Year: 1997
Tongue: English
Weight: 141 KB
Volume: 29
Category: Article
ISSN: 0538-8066
DOI: 10.1002/(sici)1097-4601(1997)29:1<35::aid-kin5>3.0.co;2-m

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✦ Synopsis

N-atom concentration profiles were measured in highly diluted C 2 N 2 /NO/Ar reaction systems behind reflected shock waves at temperatures between 3050 K and 4430 K by applying atomic resonance absorption spectroscopy (ARAS). C 2 N 2 served as a thermal source for CN radical which react with both, NO and the subsequently formed N atoms. Computer simulations based on a simplified reaction mechanism revealed strong sensitivity of the measured N atoms to the elementary reactions: CN ϩ NO NCO ϩ N (R5)

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