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N-Allylideneamines Derived from Acrolein: Synthesis and Use as Acceptors of Two Nucleophiles

✍ Scribed by Isao Mizota; Yuri Matsuda; Iwao Hachiya; Makoto Shimizu

Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 329 KB
Volume: 2009
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.200900457

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✦ Synopsis

Abstract

Two practical methods have been developed for the preparation of N‐allylideneamines 1b,c. One involves the isomerization of propargylamines and the other the dehydration of acrolein. N‐Allylideneamines 1b,c thus prepared were used as efficient substrates for 1,4‐ and 1,2‐double nucleophilic addition reactions. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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