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ChemInform Abstract: N-Allylideneamines Derived from Acrolein: Synthesis and Use as Acceptors of Two Nucleophiles.

✍ Scribed by Isao Mizota; Yuri Matsuda; Iwao Hachiya; Makoto Shimizu

Publisher: John Wiley and Sons
Year: 2009
Weight: 55 KB
Volume: 40
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200952061

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N-Allylideneamines Derived from Acrolein

N-Allylideneamines Derived from Acrolein: Synthesis and Use as Acceptors of Two Nucleophiles

✍ Isao Mizota; Yuri Matsuda; Iwao Hachiya; Makoto Shimizu 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 329 KB

## Abstract Two practical methods have been developed for the preparation of __N__‐allylideneamines **1b**,**c**. One involves the isomerization of propargylamines and the other the dehydration of acrolein. __N__‐Allylideneamines **1b**,**c** thus prepared were used as efficient substrates for 1,4‐

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ChemInform Abstract: Use of N-Allylidene-1,1-diphenylethanamine as a Latent Acrolein Synthon in the Double Nucleophilic Addition Reaction of Ketene Silyl (Thio)acetals and Allylborolanes.

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