𝔖 Bobbio Scriptorium
✦   LIBER   ✦

N-(5-Chloro-3-methyl-1-phenylpyrazol-4-ylcarbonyl)-N′-(4-methylphenyl)thiourea

✍ Scribed by Du, Hai-Tang ;Lu, Ming ;Zhou, Wei-Yi ;Sun, Li-Li

Book ID
104491707
Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
496 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The crystal structure of the title compound, C~19~H~17~ClN~4~OS, has been determined in order to elucidate the molecular conformation. The pyrazole ring makes dihedral angles of 74.3 (3)° and 2.9 (3)° with the phenyl and tolyl rings, respectively; these two six-membered rings are twisted by 71.6 (3)° with respect to each other. The crystal packing of the title compound is stabilized by intramolcular N—H...O and intermolcular N—H...S hydrogen bonds.

📜 SIMILAR VOLUMES

5-Amino-1-(5-methyl-1-phenylpyrazol-4-yl
5-Amino-1-(5-methyl-1-phenylpyrazol-4-ylcarbonyl)pyrazole-4-carbonitrile
✍ Li, Jia-Cheng ;Feng, Yu-Hong ;Lin, Qiang ;Zhang, De-La 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 989 KB

In the molecule of the title compound, C 15 H 12 N 6 O, the central pyrazole ring forms dihedral angles of 25.10 (7) and 40.22 ( 7) with the outer pyrazole and phenyl rings, respectively. In the crystal structure, centrosymmetrically related molecules are linked into dimers by intermolecular N-HÁ Á

5-Cyanomethyl-3-(4-methylphenyl)-1-pheny
5-Cyanomethyl-3-(4-methylphenyl)-1-phenylpyrazole
✍ Singh, S. K. ;Kumar, A. ;Vats, A. ;Bisht, K. S. ;Parmar, V. S. ;Errington, W. 📂 Article 📅 1995 🏛 International Union of Crystallography 🌐 English ⚖ 314 KB
N-(3-Chloro-4-fluoro­phen­yl)thio­urea
N-(3-Chloro-4-fluoro­phen­yl)thio­urea
✍ Rosli, Mohd Mustaqim ;Karthikeyan, Mari Sithambaram ;Fun, Hoong-Kun ;Razak, Ibra 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 216 KB