N′-tert-Butyl-4-chloro-N′-(4-oxo-4H-chromen-3-ylcarbonyl)benzohydrazide 0.65-hydrate
✍ Scribed by Zhao, Pei-Liang ;Huang, Wei ;Zhou, Zhong-Zhen ;Yang, Guang-Fu
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 286 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
N 0 0 0 -tert-Butyl-4-chloro-N 0 0 0 -(4-oxo-4H-chromen-3-ylcarbonyl)benzohydrazide 0.65-hydrate
📜 SIMILAR VOLUMES
2-(Arylamino)-4-oxo-4H-chromene-3-carbaldehyde 3 (R 2 = aryl) produces 12H-chromeno[2,3-b]quinolin-12-one 4 when treated with sarcosine, piperidine or diethylamine, but produces 3,3 0 -methylenebis(2-arylamino-4H-chromen-4-one) 8 when treated with the same amine in the presence of an excess of forma
In the title structure, C 24 H 17 N 2 O 2 S + ÁBr À ÁCH 3 OH, the cations, anions and solvent molecules form centrosymmetric clusters via a combination of intermolecular N-HÁ Á ÁO, O-HÁ Á ÁBr and C-HÁ Á ÁBr interactions.
In the title compound, C~23~H~25~N~3~O~3~, all bond lengths and angles show normal values. The dihedral angles between the rings of the pyrazole and the unsubstituted and __tert__-butyl-substituted benzene rings are 8.6 (2) and 78.5 (3)°, respectively, while that between the two benzene rings is 76.
In the title compound, C 19 H 20 N 2 O 5 Á0.19H 2 O, the coumarin moiety is oriented almost perpendicular to the plane of the pyrazole ring. The crystal structure is stabilized by weak intermolecular CÐHÁ Á Á% interactions.