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N-(2,5-Dichloro­phen­yl)-N′-isobutyrylthio­urea

✍ Scribed by Yusof, M. Sukeri M. ;Ariff, Norfazila M. ;Kadir, Maisara A. ;Yamin, Bohari M.


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
177 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title compound, C~11~H~12~Cl~2~N~2~OS, adopts a transcis configuration of the isobutyryl and 2,5-dichlorophenyl groups with respect to the thiono S atom, across the thiourea C—N bonds. The crystal structure is stabilized by intermolecular N—H...S hydrogen bonding, forming dimers parallel to the ac plane.


📜 SIMILAR VOLUMES


N-(2,4-Dichloro­phenoxy­acet­yl)-N′-(4-n
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In the crystal structure of the title compound, C 15 H 11 Cl 2 N 3 O 4 S, there are two intramolecular N-HÁ Á ÁO and one C-HÁ Á ÁS hydrogen bonds and a weak intermolecular C-HÁ Á ÁO hydrogen bond.

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The molecule in the title compound, C~15~H~12~Cl~2~N~2~OS, adopts a __trans__–__cis__ configuration with respect to the positions of the phenylacetyl and 3,4-dichlorophenyl groups relative to the S atom across their C—N bonds. In the crystal structure, the molecules are linked by N—H...O and C—H...O

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The title compound, C 11 H 8 Cl 2 N 2 S, was prepared from the condensation reaction of thiophene-3-carbaldehyde with 2,5dichlorophenylhydrazine. The azomethine C N bond has E geometry. No thienyl ring flip was observed.

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The title compound, C~12~H~10~Cl~2~N~2~O~2~S, was crystallized from a water–ethanol mixture. The dihedral angle between the two benzene rings is 64.86 (11)°. N—H...O and N—H...N hydrogen bonds between the NH~2~ and SO~2~ groups link molecules into layers.