N-(2,4,6-Trimethylphenyl)methanesulfonamide
✍ Scribed by Gowda, B. Thimme ;Foro, Sabine ;Fuess, Hartmut
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 484 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
The structure of the title compound, C 10 H 15 NO 2 S, resembles those of other methanesulfonanilides, with similar geometric parameters except for some differences in the bond and torsion angles. The amide H atom lies on one side of the plane of the benzene ring, while the methanesulfonyl group is on the opposite side of the plane, as in other methanesulfonanilides. The amide H atom is thus available to a receptor molecule during its biological activity. The molecules are packed into polymeric chains in the direction of the b axis through N-HÁ Á ÁO hydrogen bonds.
📜 SIMILAR VOLUMES
The title compound, [Fe(C 15 H 15 ClNS)(C 14 H 16 N)], crystallizes with the thiocarbamoyl chloride unit nearly coplanar with the cyclopentadienyl ring to which it is attached. There is a slight deviation from planarity which, along with the orientation of the amino substituent on the other cyclopen