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Cyclization of N-(2,4,6-trimethylphenyl)-β-alanines

✍ Scribed by V. Mickevicius; A. Patupaite


Publisher
Springer US
Year
2000
Tongue
English
Weight
233 KB
Volume
36
Category
Article
ISSN
0009-3122

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N-(2,4,6-Trimethylphenyl)methanesulfonam
✍ Gowda, B. Thimme ;Foro, Sabine ;Fuess, Hartmut 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 484 KB

The structure of the title compound, C 10 H 15 NO 2 S, resembles those of other methanesulfonanilides, with similar geometric parameters except for some differences in the bond and torsion angles. The amide H atom lies on one side of the plane of the benzene ring, while the methanesulfonyl group is

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N-Substituted ~.alanines have been synthesized by treating o-aminophenol or o-benzyloxyanUine with acrylic, raethacrylic, or crotonic acids. Their cyclization to 2-benzoxazolinones and dihydro.2,4(1H,3H)pyrimidinediones has been studied. We have shown [1] that, in contrast to N-aryl-B-alanines (whi