N-(2-Thiazol-2-yl)cyclopropanecarboxamide
✍ Scribed by Tian, Li ;Liu, Bin ;Wang, Jing
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 157 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C 7 H 8 N 2 OS, the thiazole ring makes a dihedral angle of 81.2 (3) with the cyclopropane ring. The amide NH group and the thiazole N atom are linked by an intermolecular N-HÁ Á ÁN hydrogen bond.
📜 SIMILAR VOLUMES
BrN 3 O, a combination of 'hard' N-HÁ Á ÁO and 'soft' C-HÁ Á ÁN interactions help to consolidate chains of molecules in the crystal structure.
The title compound, C 15 H 10 FN 3 OS, has been synthesized as a potent fungicidal agent. In the crystal structure, weak intermolecular C-HÁ Á ÁN and N-HÁ Á ÁN hydrogen bonds are found. The dihedral angles between the pyridine and thiazole rings, and between the benzene and thiazole rings, are 4.3 (
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.039 wR factor = 0.094 Data-to-parameter ratio = 14.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, C 16 H 13 N 3 OS, the plane of the -C-CH N-NH-C-bridge makes dihedral angles of 7.9 (2) and 11.9 (4) with the planes of the phenol and thiazole rings, respectively. In the molecule, there are two intramolecular interactions of type O-HÁ Á ÁN and C-HÁ Á ÁN. In the crystal struc