In the title compound, C 7 H 8 N 2 OS, the thiazole ring makes a dihedral angle of 81.2 (3) with the cyclopropane ring. The amide NH group and the thiazole N atom are linked by an intermolecular N-HÁ Á ÁN hydrogen bond.
N-(5-Bromopyrimidin-4-yl)cyclopropanecarboxamide
✍ Scribed by Walji, Dhiran V. B. ;Storey, John M. D. ;Harrison, William T. A.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 207 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
BrN 3 O, a combination of 'hard' N-HÁ Á ÁO and 'soft' C-HÁ Á ÁN interactions help to consolidate chains of molecules in the crystal structure.
📜 SIMILAR VOLUMES
The title compound, C 14 H 12 BrN 2 O + ÁClO 4 À , was synthesized from the parent 2-aminooxazole and acetylacetone and characterized by 1 H NMR and single-crystal X-ray diffraction. The bromophenyl fragment and the essentially planar ninemembered bicyclic system form a dihedral angle of 10.50 (11)
The title compound, C 18 H 20 ClN 3 O 2 , is a potent new herbicide. X-ray analysis reveals that the benzene ring is twisted away from the isoxazole ring by 67.7 (1) . The crystal packing is stabilized by intermolecular N-HÁ Á ÁN and C-HÁ Á ÁO hydrogen bonds.