The title compound, C~23~H~19~ClN~2~O~2~, has been obtained by the reaction of (__Z__)-4-(4-chlorobenzylidene)-2-phenyloxazol-5(4__H__)-one and benzylamide. The molecules are connected by two N—H...O intermolecular hydrogen bonds to form helicoidal chains running parallel to the __c__ axis.
N-(2-Chlorophenyl)benzamide
✍ Scribed by Gowda, B. Thimme ;Sowmya, B. P. ;Kožíšek, Jozef ;Tokarčík, Miroslav ;Fuess, Hartmut
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 570 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the structure of the title compound (N2CPBA), C 13 H 10 ClNO, the conformation of the N-H bond is anti to the ortho-Cl substituent in the aniline benzene ring. It closely resembles the structure of 2-chloro-N-phenylbenzamide (NP2CBA), although the two amides crystallize in different crystal systems. The molecules of N2CPBA are linked into a chain through an N-HÁ Á ÁO hydrogen bond.
📜 SIMILAR VOLUMES
The title compound, C~13~H~10~N~2~O~2~, has a __Z__,__Z__ (__trans__–__trans__) arrangement of the central CONHCO group and an intramolecular N—H...N hydrogen bond. The molecule has a twisted conformation; the pyridine ring, which is almost parallel to the plane of the amide function at position 2,
The molecule of the title compound, C~20~H~14~N~2~O~3~, a tertiary amine with one 2-pyridylcarbonyl and two benzamide substituents, is shaped like a propeller. In the crystal structure, molecules related by a center of symmetry are linked by C—H...O hydrogen bonds to form dimers. These dimers are li