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N-(2-Pyridylcarbonyl)benzamide

✍ Scribed by Gasser, Gilles ;Stoeckli-Evans, Helen

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 206 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807008355

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✦ Synopsis

The title compound, C~13~H~10~N~2~O~2~, has a Z,Z (trans–trans) arrangement of the central CONHCO group and an intramolecular N—H...N hydrogen bond. The molecule has a twisted conformation; the pyridine ring, which is almost parallel to the plane of the amide function at position 2, is inclined to the phenyl ring by 50.05 (6)°. In the crystal structure, symmetry-related molecules are linked by C—H...O hydrogen bonds, forming a zigzag polymer chain extending in the a-axis direction. The chains are linked by a C—H...π interaction involving phenyl rings of adjacent chains. There is also a π–π interaction involving pyridine rings related by a center of symmetry.

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✦ Synopsis

N-(2-Pyridylcarbonyl)benzamide