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Mössbauer effect of 129I in the bridged and isolated forms of mercury (II) iodide

✍ Scribed by Hiroshi Sakai; Yutaka Maeda; Sumio Ichiba; Hisao Negita

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
286 KB
Volume
27
Category
Article
ISSN
0009-2614

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✦ Synopsis

The Mijssbauer effect of the 27.8 keV transition in "'1 IWS observed to investigate the electronic structure of mercury (II) iodide in the bridged and isolated forms. From hlSssbnuer parameters such as the isomer shift, the qundrupole coupling constant, and the asymmetry pnrameter, the electronic confipurntions of iodine were derived lo be 5s'.975ps.27 and 5s2sp5.52 for the bridged and isolated forms, respectively. The s-character in rhe iodine bond MU found to be 4 c/o and the quodrupole coupling constant was positive for the bridged form. On the other hand, the quadrupole coupling constant was negative and its absolute value was larger for rhe isolated form. Based on these results, the bond character of iodine in mercury (II) iodide was discussed.

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