Mössbauer and magnetic properties of several europium intermetallic compounds
✍ Scribed by H.H. Wickman; J.H. Wernick; R.C. Sherwood; C.F. Wagner
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- English
- Weight
- 117 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0038-1098
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EuPd 3 S 4 with a NaPt 3 O 4 -type structure was investigated by X-ray di4raction, 151 Eu MoK ssbauer spectroscopy, magnetic susceptibility, and speci5c heat measurements. In this compound, Eu 2؉ and Eu 3؉ ions exist in the ratio of ca. 1:1. The Debye temperatures of Eu 2؉ and Eu 3؉ were determined
The quasi-particle character off electrons (due to band mixing) in Eu chaicogenides, giving rise to Anderson's superexchange, is involved in order to correlate Mdssbauer parameters to bulk magnetic properties (isomer shifts and hyperfine fields). In this note we intend to discuss, in the light of r