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Multicomponent Synthesis of Piperidinium 3,5-Dicyano-4-cyclohexanespiro-2-oxo-1,2,3,4-tetrahydropyridine-6-thiolate

โœ Scribed by S.G. Krivokolysko; K.A. Frolov; V.P. Litvinov


Book ID
110304216
Publisher
Springer US
Year
2001
Tongue
English
Weight
91 KB
Volume
37
Category
Article
ISSN
0009-3122

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ChemInform Abstract: Ethylcrotonates in
โœ V. D. DYACHENKO; A. A. NIKISHIN; V. P. LITVINOV ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 2 views

Ethylcrotonates in the Synthesis of 4,4-Disubstituted 3,5-Dicyano-6oxo-1,4,5,6-tetrahydropyridine-2-thiolates. -Michael addition of ethyl crotonate (I) to cyanothioacetamide (II) in the presence of N-methylmorpholine and subsequent in situ cyclization affords the title tetrahydropyridinethiolates as