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MTO catalyzed oxidation of aldehyde N,N-dimethylhydrazones with hydrogen peroxide: high yield formation of nitriles and N-methylene-N-methyl N-oxide

✍ Scribed by Rudler, Henri; Denise, Bernard

Book ID
120229610
Publisher
Royal Society of Chemistry
Year
1998
Tongue
English
Weight
53 KB
Volume
19
Category
Article
ISSN
1359-7345

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πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: MTO Catalyzed Oxida
ChemInform Abstract: MTO Catalyzed Oxidation of Aldehyde N,N-Dimethylhydrazones with Hydrogen Peroxide: High Yield Formation of Nitriles and N-Methylene-N-methyl N-Oxide.
✍ H. RUDLER; B. DENISE πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 26 KB πŸ‘ 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

High-yield synthesis of nitriles by oxid
High-yield synthesis of nitriles by oxidation of aldehyde N,N-dimethylhydrazones with dimethyldioxirane
✍ Anna Altamura; Lucia D'Accolti; Antonia Detomaso; Anna Dinoi; Michele Fiorentino πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 270 KB

Using dimethyldioxirane, the selective transformation of aldehyde N,N-dimethylhydrazones into the corresponding nitriles was achieved in high yield and under mild conditions. The determination of the substituent effect on rates, along with an estimate of the primary kinetic isotope effect using PhCH