Oxidation of Aldehyde N,N-Dialkylhydrazones with Hydrogen Peroxide. A New Nitrile Synthesis
β Scribed by Smith, Richard F.; Albright, James A.; Waring, Anne M.
- Book ID
- 118154197
- Publisher
- American Chemical Society
- Year
- 1966
- Tongue
- English
- Weight
- 377 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0022-3263
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Using dimethyldioxirane, the selective transformation of aldehyde N,N-dimethylhydrazones into the corresponding nitriles was achieved in high yield and under mild conditions. The determination of the substituent effect on rates, along with an estimate of the primary kinetic isotope effect using PhCH