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Oxidative Cleavage of N , N -Dimethylhydrazones to Ketones with Hydrogen Peroxide, Catalyzed by Methyltrioxorhenium(VII)

✍ Scribed by Stanković, Saša; Espenson, James H.

Book ID
126994628
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
90 KB
Volume
65
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Oxidative Cleavage
ChemInform Abstract: Oxidative Cleavage of N,N-Dimethylhydrazones to Ketones with Hydrogen Peroxide, Catalyzed by Methyltrioxorhenium(VII)
✍ Sasa Stankovic; James H. Espenson 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Methyltrioxorhenium-catalyzed oxidation
Methyltrioxorhenium-catalyzed oxidation of aldehyde and ketone N,N-dimethylhydrazones with H2O2: formation of nitriles from aldehydes and regeneration of the ketones
✍ Henri Rudler; Bernard Denise; Stéphane Masi 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 274 KB

N,N-dimethylhydrazones of aldehydes can be efficiently oxidized in a catalytic way by hydrogen peroxide associated with methyltrioxorhenium (MTO) as the catalyst to give nitriles. Elimination of dimethylhydroxylamine that is further oxidized to N-methyl-N-methylene N-oxide takes place. This nitrone