Monomolecular chain termination in the kinetics of dimethacrylate postpolymerization
β Scribed by Y. G. Medvedevskikh; A. R. Kytsya; L. I. Bazylyak; A. M. Bratus; A. A. Turovski; G. E. Zaikov
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 111 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0021-8995
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π SIMILAR VOLUMES
The photosensitized polymerization of styrene in bulk was investigated in the temperature range of 25-70Β°C with respect to the average rate coefficient of bimolecular chain termination k t , especially its chain length dependence at low conversions, by means of pulsed laser polymerization (PLP). Thr
It is shown that the (established) method of deriving chain-length distributions from propagation probabilities is not fully consistent with the Poissonian character of chain propagation if termination is chain-length dependent: the fluctuation of chain propagation leads to somewhat lower radical co